1. Create a new image.
2. Set the guide(s) for the mirroring.
3. Create half the shape.
4. Duplicate the shape half.
5. Flip the shape half.
6. Align the 2 halves.
7. Combine the 2 halves.
8. Select Define Custom Shape from the Edit menu.
9. Choose the Shape tool.
10. Switch to the Custom shape tool.
11. Click on the Custom Shape Picker on the Options bar.
12. Choose Save Shapes from the Shape Picker pop-up menu.